Polytetrahydrofuran Structure25190-06-1

Polytetrahydrofuran Structure25190-06-1

Polytetramethylene ether glycol, referred to as PTMEG, is a homopolymer obtained by cationic ring-opening polymerization of the monomer tetrahydrofuran (THF) in the presence of a catalyst, which is a linear polyetherdiol with primary hydroxyl terminal group
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Product Introduction
Product Introduction

 

Polytetrahydrofuran Structure 25190-06-1 (PTMEG), identified by CAS 25190-06-1, is a homopolymer produced via cationic ring-opening polymerization of tetrahydrofuran (THF) monomer with the aid of a catalyst. Classified as a linear polyether diol, it features primary hydroxyl groups at its terminals. The molecular makeup of this compound is defined by recurring –(CH₂)₄O– units, and it comes in various grades based on relative molecular weight, including 650, 1000, 1800, 2000, and 2900 Da. Notably, industrial manufacturing allows for adjustments to molecular weight as per market requirements, enabling the production of diverse specifications.​
 

At room temperature, PTMEG appears as a white waxy solid with a melting point ranging from 30 to 35°C; beyond this temperature range, it transitions into a clear, colorless liquid. It exhibits good solubility in alcohols, esters, ketones, aromatic compounds, and chlorinated hydrocarbons, while remaining insoluble in aliphatic hydrocarbons and water. Its primary application lies in the realm of high-performance elastomers.

 

Quality Index

 

product-1078-328

product-1078-279

product-1073-251

 

Product features

 

Polytetrahydrofuran uses natural gas as raw material and is produced using the heterogeneous catalyst process of the American company Invista. The product quality is in a leading position in the world. In January 2013, it passed the INVISTA PTMEG commercial qualification certification and became the first company in China to obtain the INVISTA PTMEG technology license. manufacturer, and its products are used by many companies such as Foshan Invista and Huafeng Spandex, and have received unanimous praise. Our company can provide customers with high-quality 1000, 1800, 2000 and other molecular weight products.

 

Product use

 

1.Mainly used for the production of polyurethane elastomer, spandex and ester ether copolymer elastomer.

2.Thermoplastic polyurethane produced with PTMEG as raw material is widely used in petrochemical, machinery, military, shipbuilding, automobile, synthetic leather and other industries.

3.It is widely used in the production of coatings and surfactants.
 

Molecular Structure Applications

 

 

Spandex fibers
Soft segment for Lycra-type elasticity

TPU production
Polyol for shoe soles/adhesives

PEBA resins Copolyamide for sports gear

Hydraulic seals Hydrolysis-resistant urethanes

Coating flexibilizers
UV-stable polyethers

 

 

 
 
Key Structural Specifications

Parameter

Specification

CAS No

25190-06-1

Molecular Weight

650/1000/1800/2000/2900 ±50Da

OH Value (mg KOH/g)

56.1 (2000Da) – 169.0 (650Da)

Unsaturation (meq/g)

≤0.04

Viscosity @ 40°C (cSt)

300 (2000Da) – 60 (650Da)

Water Content

≤0.025%

 

Industrial Processing Protocol

 

 

 

1

 

TPU Synthesis

 React with MDI @ 80-100°C (NCO:OH=1.02)

2

 

Spandex Spinning

 35-45% PTMEG content in dry-spun fibers

3

 

Storage

 Nitrogen-blanketed stainless steel totes

4

 

Thermal Limit

 Degrades >150°C – monitor exotherm

 
 

 

 
 
Performance Validation Data
product-150-100

For Spandex Fibers:

Elastic recovery: ≥95% after 300% stretch

Tenacity: 0.8–1.2 g/denier

Yellowing resistance: Δb* <1.0 (500h UV)

product-150-100

For TPU Applications:

Shore hardness: 70A–95A (2000Da MW)

Tear strength: 60–120 kN/m

Low-temp flexibility: -60°C pass

 

Failure Prevention
 
 
 

Viscosity drop

Limit storage temp <50°C

 
 

Peroxide formation

Add 200ppm BHT inhibitor

 
 

Crystallization

Maintain 30-40°C in transfer lines

 
 

Color shift

Exclude copper alloy contact

 

 

 

 

Storage and transportation conditions

 

Bulk can be filled by tankers, tankers and ISO tanks, all of which are insulated and equipped with heating coils.

Storage: Nitrogen, not with strong inorganic oxidants (e.g. nitric acid), moisture-absorbent, keep container tightly closed, preferably at temperatures above 45°C (113°F) to prevent solidification.

 

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